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3-Cyano-6-isopropylchromone

$96

Brand : BIOFRON
Catalogue Number : BN-O1014
Specification : 98%(HPLC)
CAS number : 50743-32-3
Formula : C13H11NO2
Molecular Weight : 213.23
PUBCHEM ID : 736017
Volume : 5mg

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Catalogue Number

BN-O1014

Analysis Method

Specification

98%(HPLC)

Storage

2-8°C

Molecular Weight

213.23

Appearance

Botanical Source

Structure Type

Category

SMILES

CC(C)C1=CC2=C(C=C1)OC=C(C2=O)C#N

Synonyms

3-cyano-6-isopropylchromone/6-(1-methylethyl)-4-oxo-4H-1-benzopyran-3-carbonitrile/6-Isopropyl-4-oxo-4H-chromene-3-carbonitrile/6-Isopropylchromone-3-carbonitrile/6-isopropyl-4-oxo-4H-1-benzopyran-3-carbonitrile

IUPAC Name

4-oxo-6-propan-2-ylchromene-3-carbonitrile

Density

1.2g/cm3

Solubility

Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.

Flash Point

139.3ºC

Boiling Point

320.4ºC at 760 mmHg

Melting Point

InChl

InChI=1S/C14H10O5/c1-6-2-7(15)5-11-12(6)9-3-8(16)4-10(17)13(9)14(18)19-11/h2-5,15-17H,1H3

InChl Key

IMVAJLIIWCJMJP-UHFFFAOYSA-N

WGK Germany

RID/ADR

HS Code Reference

Personal Projective Equipment

Correct Usage

For Reference Standard and R&D, Not for Human Use Directly.

Meta Tag

provides coniferyl ferulate(CAS#:50743-32-3) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. Articles of coniferyl ferulate are included as well.>> amp version: coniferyl ferulate

No Technical Documents Available For This Product.

PMID

31406482

Abstract

Pristimantis is the most diverse genus of tetrapods comprising 532 described species. It contains a large number of morphologically cryptic species that are being discovered with the assistance of genetic evidence. We use molecular, morphological, bioacoustic, and environmental data to assess the phylogenetic relationships and determine the species within an Andean clade of Pristimantis, which is distributed from central Ecuador to northern Peru. We assign to this clade the name Huicundomantis and propose it as a subgenus. Our results show that Huicundomantis is composed of two large clades which we name as the P. phoxocephalus species group and the P. cryptomelas species group. Huicundomantis is composed of 28 species of which 12 have been described and 16 are new. We describe 11 of these undescribed species. The most effective characters to discriminate among species are DNA sequences, qualitative morphology, and advertisement calls. Morphometric and environmental characters are not very useful to define species limits. We clarify the identity of P. riveti and show that populations from southern Ecuador traditionally ascribed to P. riveti are a new species, P. lutzaesp. nov. We also show that P. prometeii is a junior synonym of P. hampatusami. The current diversity and geographic distribution of Huicundomantis are consistent with a model of allopatric speciation. All species have a restricted distribution range (less than 4330 km2) and are assigned to the Red List categories Data Deficient or threatened with extinction. We provide new reasons to increase conservation efforts for these species and their habitat. Taking our results into account, Pristimantis species richness in Ecuador increases from 211 to 221 species, and the number of species endemic to Ecuador from 119 to 129.

KEYWORDS

Andes, cryptic diversity, integrative taxonomy, Neotropics, Pristimantis phoxocephalus species group, P. cryptomelas species group

Title

Systematics of Huicundomantis, a new subgenus of Pristimantis (Anura, Strabomantidae) with extraordinary cryptic diversity and eleven new species

Author

Nadia B. Paez1,2 and Santiago R. Roncorresponding author1

Publish date

2019;

PMID

31523466

Abstract

The synthesis, crystal structure and structural motif of two thio­phene-based cyano­acrylate derivatives, namely, ethyl (E)-2-cyano-3-(3-methyl­thio­phen-2-yl)acrylate (1), C11H11NO2S, and ethyl (E)-2-cyano-3-(thio­phen-2-yl)acrylate (2), C10H9NO2S, are reported. Derivative 1 crystallized with two independent molecules in the asymmetric unit, and derivative 2 represents a new monoclinic (C2/m) polymorph. The mol­ecular conformations of 1 and the two polymorphs of 2 are very similar, as all non-H atoms are planar except for the methyl of the ethyl groups. The inter­molecular inter­actions and crystal packing of 1 and 2 are described and compared with that of the reported monoclinic (C2/m) polymorph of derivative 2 [Castro Agudelo et al. (2017 ▸). Acta Cryst. E73, 1287-1289].

KEYWORDS

crystal structure, thio­phene-based cyano­acrylates, polymorph, crystal supra­molecularity

Title

Synthesis, characterization, crystal structure and supra­molecularity of ethyl (E)-2-cyano-3-(3-methyl­thio­phen-2-yl)acrylate and a new polymorph of ethyl (E)-2-cyano-3-(thio­phen-2-yl)acrylate

Author

Mahmoud Al-Refai,a Basem F. Ali,a,* Ala’a B. Said,a Armin Geyer,b Michael Marsch,b and Klaus Harmsb

Publish date

2019 Sep 1;

PMID

24454060

Abstract

In the title hydrated salt, C6H7N2O2 +·C7H5O6S−·H2O, the benzene ring of the cation makes a dihedral angle of 1.32 (19)° with the attached nitro group. In the anion, an intra­molecular O—H⋯O hydrogen bond with an S(6) ring motif is formed between the carb­oxyl and hy­droxy groups; the dihedral angle between the carb­oxyl group and the benzene ring is 8.76 (8)°. The crystal structure exhibits inter­molecular N—H⋯O, O—H⋯O, C—H⋯O, and π-π [centroid-centroid distances = 3.6634 (9) and 3.7426 (9) a] inter­actions to form a three-dimensional network.

Title

4-Nitro­anilinium 3-carb­oxy-4-hy­droxy­benzene­sulfonate monohydrate

Author

P. K. Sivakumar,a M. Krishna Kumar,b G. Chakkaravarthi,c,* R. Mohan Kumar,b and R. Kanagaduraib,*

Publish date

2013 Nov 1